Another very important compound, composed of nitrogen and hydrogen combined in molecular form as NH₃, is ammonia. Its fate is important in assessments because it is part of the nitrogen cycle, acting in effect as the critical intermediate in transforming nitrogen into forms usable by plants and other organisms.
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Moreover, the application of ammonia in agriculture as a fertilizer and its impact on environmental health—through eutrophication and atmospheric pollution—make studies on this molecule very essential. This paper will present a summary of the production of ammonia, its transformation in different ecosystems, and the environmental implications of its presence and movement.
Ammonia is produced from the following sources:
Decomposition of organic matter
This occurs in the natural decaying of plants and remains of animals that emit ammonia into the soil.
Animal waste
Excretes from domestic and wild animals excrete quite large amounts of ammonia to the environment.
Agricultural activities
Application of nitrogen-based fertilizers and rearing animals leads to the emission of ammonia.
The manufacturing processes of numerous chemicals, like fertilizers and plastics, emit ammonia.
Wastewater treatment
Wastewater from sewage and industrial waste results in the production of ammonia.
The nitrogen cycle is the process through which nitrogen is transformed from one of its chemical forms to another. This is a change that holds a significant value to the existence of life on this Earth.
An important intermediate in the nitrogen cycle is formed by the decay of organic matter. This is also the starting substance for several conversion processes
Nitrification: Ammonia gets oxidized to nitrites and then to nitrates, that too by the nitrifying bacteria, hence making nitrogen available to plants in a usable form.
Ammonification: It is the conversion of organic nitrogen into ammonia, done by decomposers like bacteria and fungi. This replaces the amount of ammonia in the soil and hence continues the cycle of nitrogen.
The effect on ammonia varies based on the type of environment:
All ammonia can potentially bind to soil particles therefore making the ammonium less available for uptake by plants but more stable in the soil
Soil microorganisms convert through oxidation the ammonia into nitrites and nitrates- plant-absorbable forms.
These nitrates turn over and get again reduced into nitrogen gas through denitrification and released into the atmosphere.
Ammonia is easily soluble in water; hence, its concentration and bioavailability will vary in aquatic systems.
Ammonia can easily and readily be absorbed by aquatic plants and microorganisms.
It can readily provide the much-needed Nutrition that the said organisms can easily utilise.
On the contrary, large doses of ammonia represent lethal doses to fish and other forms of aquatic life.
Ammonia is reduced to nitrite and nitrate through microbial action the same as that in soil, and all these processes are of equal importance in the aquatic nitrogen cycle.
The ammonia can be volatilised in the atmosphere, mainly from soil and water under high temperatures and alkaline conditions.
In the atmosphere itself, ammonia can react with acids to form ammonium salts, which affect air quality and atmospheric chemistry.
Through precipitation or any other kind of dry deposition, O-ammonia and other derivative products get re-deposited back to the earth's surface and finally find their way into the earth's soil and water systems to enter into the cycle of nitrogen again.
The ammonia changes into other nitrogen compounds, like nitrate and nitrite, by different chemical and biological reactions of concern for the quality of the soil, water, and air.
Ammonia is but one extremely important factor in the nitrogen cycle having roles in nitrification and ammonification processes as a basis for a proper balance in ecosystems.
Natural sources of ammonia emissions include the variety associated with organic matter and decomposition of dung, while anthropogenic sources include those dealing with agriculture, industries, and wastewater treatment.
Respiratory and skin problems are just some serious health hazards that could be caused by ammonia exposure at higher concentrations, with the ensuing serious conditions determined by the length of time exposed.
Control of the emission of ammonia can be ensured by better agricultural practices, industrial emission controls, efficient treatment of wastewater, and rigorous enforcement of environment-related laws and regulations.
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