Structure of Benzene - Discovery, Lewis Structure, Properties, FAQs

Introduction: What is Structure of Benzene

Benzene is said to be an organic chemical compound containing carbon and hydrogen. The molecular formula of benzene is C₆H₆. This suggests that benzene is composed of six carbon atoms and six hydrogen atoms. These atoms are joined together in a planar ring and to each carbon atom, one hydrogen atom is attached. The benzene structural formula can be drawn in the following manner:

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This Story also Contains

1. Introduction: What is Structure of Benzene
2. Discovery of Benzene
3. Properties and Occurrence of Benzene
4. Uses of Benzene

In an alternate position, it contains double bonds; this double bond shows that benzene is unsaturated in nature. Those compounds which contain double or triple bonds are said to be unsaturated in nature while those who have only a single bond are saturated in nature. Benzene is also kept in the category of hydrocarbons, these compounds are made up of carbon and hydrogen only.

Benzene formula or benzene chemical formula is C₆H₆.

C₆H₆ the chemical name is benzene.

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Discovery of Benzene

Benzene was discovered by European pharmacists in the 16^th century and the word benzene is basically derived from the word gum benzoin or we can call it benzoin resin which is known as aromatic resin. Aromatic compounds have ring-like structures. Benzene is said to be aromatic in nature and the aromaticity concept can also be explained with the help of Huckel’s rule this rule states that a compound that contain electrons is aromatic in nature, In the case of benzene n = 1 and it contains electrons i.e. aromatic in nature.

Structure

Benzene structure contains six carbon bonds and six hydrogen bonds with alternating double bonds. According to X-ray diffraction, all the six carbon-carbon bonds are of equal length and it is measured to be 140 picometers. There is a slight difference between double and single carbon-carbon bonds. The C-C double bond is greater in length as compared to a single C-C bond this difference can be explained on the basis of delocalization as in the case of double bond electrons are equally distributed to all the six carbon atoms.

Benzene and cyclohexane almost contain similar structures, the only difference is the loss of one hydrogen per carbon in the ring of delocalized electrons which makes it a different kind of cyclohexane. The shape of the molecule is said to be of planar nature. The molecular orbital of benzene generally involves the formation of three delocalized electrons which revolves around all six carbon atoms and gives resonating structures. Resonating structures involve the revolution of double bonds and it gives two stable resonating structures. The resonating structures of benzene can be shown as follows:

It is said to be highly stable in nature and due to its chemical properties, these are aromatic in nature. The nature of the bonding of benzene is exactly described with the cyclic hexagonal shape of six carbon atoms.

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Lewis Structure of Benzene

The Lewis structure of any compound is shown by the valence shell electrons of that molecule. It generally tells us the arrangement of electrons in a molecule with the help of dot representation and can also be known as electron dot structure. In this type of structure, each bond is shown with the help of two dots between two atoms.

Lewis structure of benzene can be derived by using a number of steps given follow:

1. First step generally involves the determination of the total number of valence electrons of every atom present in benzene and it can be calculated by combining the valence electrons of carbon and hydrogen.

Valence electrons are those electrons that are present in the valence shell of that atom.

Number of carbon atoms in benzene = 6

Valence electrons in carbon = 4

Carbon has atomic number 6 so electron distribution in K, L shell is 2, 4 and in the outermost shell L shell which is its valence shell contains 4 electrons which correspond that it has valency 4.

Number of hydrogen atoms in benzene = 6

Valence electrons in hydrogen = 1

An atomic number of hydrogen is 1 so it contains valence electrons in the outermost shell and has valency 1.

Now, the Total number of the valence electrons in carbon =

Total number of the valence electrons in hydrogen =

2. Now determine the total number of valence electrons in benzene

Total number of valence electrons in benzene = Total number of valence electrons in carbon + Total number of valence electrons in hydrogen

= 24 + 6 = 30 electrons.

3. Step 3 involves the need for electrons to complete their octet

In the case of carbon 6 electrons are divided into two subshells K and L, subshell K contains 2 and electrons and L contains 4 electrons, here in this case K subshell is already filled and L have 4 electrons this corresponds that L subshell needs 4 more electrons to complete its octet. In the case of a hydrogen atom, it contains only 1 electron which is filled in K subshell and it contains at most 2 electrons so hydrogen needs only 1 electron to complete its octet. This corresponds to each carbon atom forming a single bond with one hydrogen atom.

Electron Dot structure of benzene can be shown as:

In this case, hydrogen atoms are paired but each carbon atom will need 3 more electrons for its outermost shell.

4. Number of electrons needed to acquire stable configuration

Now, according to the structure given in point 3, it is clear that each carbon atom needs 3 more electrons to complete its octet and there are 6 carbon atoms in benzene so as to total it needs 18 electrons to attain a stable configuration. This corresponds to the remaining electrons being placed in such a manner that it completes the octet of a carbon atom. The final dot structure of benzene can be shown in the following manner:

Like in this case 2 dots correspond to a single bond while 4 dots correspond to double bond atoms. This gives us the true structure of the benzene atom which contains alternative double bonds.

5. Lewis structure of benzene

This information tells us that benzene contains six carbon atoms attached in a planar ring with alternate double and single bonds and each carbon is attached to one hydrogen atom with the help of a single bond. structure of benzene can be shown as:

We can also show this structure in three-dimensional form which can be shown as:

This can also be shown as a normal aromatic ring or like cyclohexane structure with the presence of double bonds this can be shown as:

Properties and Occurrence of Benzene

Benzene is said to be highly flammable in nature. It is said to be a volatile compound and has a gasoline-like smell. It can be found in the oil-refining process as a side product along with crude oil. It can also be found by naturally occurring substances like a forest fire which is present in plants and animals. It is a clear and colorless liquid. The molar mass of benzene is 78.11 g/mol and slightly soluble in water but easily soluble in organic solvents. Its density is less than water.

Uses of Benzene

Benzene has a number of industrial uses like it is used in the preparation of phenol, aniline which is further used in dyes, and dodecylbenzene in detergents. In the preparation of other chemicals like ethylbenzene, cyclohexane, alkylbenzene, nitrobenzene etc. It can also use in the manufacturing of nylon fibers.

Benzyne

Benzyne is the main substituent derived from benzene; it is said to be a highly reactive species that are derived from the aromatic ring by removal of two substituents and it contains a triple bond. The structure of the benzyne atom can be shown as follows:

The molecular formula of benzyne is .

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