The full form of HDPE & LDPE is -
HDPE - High-density polyethylene
LDPE - Low-density polyethylene
High-density polyethylene (HDPE) is a thermoplastic polymer made out of the monomer ethylene. Also referred to as "alkathene" or "polythene", widely used for HDPE pipes. Its chemical formula can be generalized as (C2H4)n.
Low-density polyethylene (LDPE) is a thermoplastic crafted from the monomer ethylene. It became the first grade of polyethylene, produced in 1933 via Imperial Chemical Industries (ICI) the usage of a high strain manner via unfastened radical polymerization.
Density-940 kg/m3
Melting factor 130.8 °C.
Temperature of crystallization 111.9 °C.
Latent warmness of fusion 178.6 kJ/kg.
Thermal conductivity 0.44 W/m.°C. at °C.
Particular warmth capacity 1330 to 2400 J/kg-K
Crystallinity-60%
HDPE is understood for its high electricity-to-density ratio.The density of HDPE tiers from 930 to 970 kg/m3.The density of HDPE is best marginally higher than that of low-density polyethylene, HDPE has little branching, giving it stronger intermolecular forces and tensile energy than LDPE. The difference in energy exceeds the difference in density, giving HDPE a better unique energy.it's also more difficult and extra opaque and can face up to incredibly better temperatures (120 °C/248 °F for quick intervals). Excessive or high-density polyethylene, unlike polypropylene, can't face up to typically required autoclaving situations. The scope of branching is ensured by the precise desire of catalyst (e.g., Ziegler–Natta catalysts) and reaction situations.HDPE is proof against many exceptional solvents, so it can not be glued.
3-D printer filament
arena board (% board)
Backpacking frames
Ballistic plates
Banners
Bottle caps
LDPE is defined with the aid of a density variety of 917–930 kg/m3.
At room temperature it is not reactive, except to sturdy oxidizers; some solvents reason it to swell.
Made in translucent and opaque versions, it is quite bendy and tough.
Excellent resistance (minor assault/very low chemical reactivity) to aldehydes, ketones, and vegetable oils.
Facial wash gel bottle manufactured from LDPE.
Polyolefins (LDPE, HDPE, PP) are a major form of thermoplastic.
LDPE is extensively used for production diverse packing containers, allotting bottles, wash bottles, tubing, plastic components like use is in plastic baggage.
Trays and trendy purpose containers.
Corrosion-resistant work surfaces.
The polymer chains that make up each materials are branched in LDPE, whereas in HDPE, the polymers have a greater crystalline shape.
LDPE is softer and more flexible than HDPE. It additionally has a decrease melting factor (one hundred fifteen° C) and is more obvious. as compared to HDPE, it's miles much more likely to crack under strain.
HDPE is inflexible and durable and offers greater chemical resistance. Its better melting point (135° C) lets in it to resist higher temperatures than LDPE. Its greater crystalline shape also results in more energy and opacity of the material.
Its popular manufacture entails the compression of ethylene fuel, polymerisation with the use of an initiator, and fuel separation.
Most of the HDPE materials are produced by using both slurry polymerisation or gas section polymerisation. The procedure starts with polymerisation from a solution of ethylene monomers, accompanied by using separation and drying.
The polymer chains of LDPE are particularly branched compared to HDPE. This branching prevents the chains from stacking neatly beside each other, decreasing the intermolecular forces of attraction. This outcomes in a plastic this is softer and extra bendy, however which also has lower tensile power.
No,because LDPE is hydrophobic and has no tendency of soaking up water.
HDPE has greater stiffness, tension, warmness resistance, and elevated resistance to permeability than LDPE.
HDPE is manufactured at low temperatures and pressures with the use of Ziegler-Natta catalysts.