The full form of MnO2 is Manganese dioxide. Manganese dioxide known as pyrolusite when found in nature is the most plentiful of all the manganese compounds. Manganese dioxide which is MnO2 is a black-brown solid that occurs naturally. It is a metal oxide and manganese molecular entity. Manganese dioxide occurs naturally and contains impurities as well as a significant amount of manganese(III) oxide.
Manganese dioxide reacts with potassium hydroxide in the presence of oxygen and forms potassium permanganate.
4 \mathrm{MnO}_2+4 \mathrm{KOH}+3 \mathrm{O}_2 \rightarrow 4 \mathrm{KMnO}_4+2 \mathrm{H}_2 \mathrm{O}
Manganese dioxide combines with aluminium to form aluminium oxide and water. The chemical equation is as below,
3 \mathrm{MnO}_2+4 \mathrm{Al} \rightarrow 2 \mathrm{Al}_2 \mathrm{O} _3+3 \mathrm{Mn}+\text { heat }
Manganese dioxide is odourless.
The complexity number of manganese dioxide is 18.3.
The oxidation number of MnO2 is +4.
2 is the hydrogen bond acceptor for MnO2.
When the blackish compound MnO2 is fused with KOH in the presence of air, it produces the dark green compound Potassium manganate.
2 \mathrm{MnO}_2+4 \mathrm{KOH}+\mathrm{O}_2 \rightarrow 2 \mathrm{~K}_2 \mathrm{MnO}_4+2 \mathrm{H}_2 \mathrm{O}
MnO2 is primarily found in dry-cell batteries.
Almost all raw materials used in the ceramic industry to make glass contain some iron, usually in the form of ferric oxide.
Used in glass making to remove the green tint caused by iron impurities.
Used as an important component in batteries. The positive electrode carbon in the Leclanche cell is surrounded by manganese dioxide and carbon.
Manganese dioxide is a natural filter media that effectively removes iron, manganese and Sulphur odour from well water.
MnO2 can significantly accelerate the oxidation kinetics of phenolic compounds such as triclosan and chlorophenols by potassium permanganate in slightly acidic solutions.
MnO2 can act as an oxidising agent as well as a reducing agent.
Manganese dioxide is a positive catalyst used in the decomposition of hydrogen peroxide.
Among all the transition metal oxides, MnO2, which exhibits stable performance in supercritical water oxidation (SCWO), has a relatively high catalyst activity in the catalyst decomposition of organic compounds by oxidation.