Phosphorus pentoxide is a chemical compound with the molecular formula P4O10 and the empirical formula P2O5. This chemical occurs as a white solid that is crystalline at room temperature. Phosphorus pentoxide is a phosphoric acid-derived acid anhydride. Since it is very hygroscopic, it is employed as a dehydrating agent and a desiccant.
It is a microcrystalline, white, light powder produced by burning elemental phosphorus in excessive oxygen. The anhydride of orthophosphoric acid is phosphorus pentoxide. It is very hygroscopic and is transformed into orthophosphoric acid by water via intermediates. The interaction with water is intense and produces a huge amount of heat. Phosphorus pentoxide's capacity to flow may vary in a particular range due to its hygroscopic and microcrystalline nature. Furthermore, producing fragile agglomerates that disintegrate under moderate pressure is unavoidable. It is an effective desiccant and dehydrator.
Phosphorus pentoxide crystallises in at least four different forms, known as polymorphs. The most common is a metastable form. Molecules are held together by weak van der Waals forces. It has a density of 2.30 g/cm3 . It can sublimate if heated quickly enough. This form is created by rapidly condensing the vapour of phosphorus pentoxide, resulting in a very hygroscopic solid.
The phosphorus atoms are joined by a tetrahedron of oxygen atoms, one of which produces a terminal P=O bond by giving terminal oxygen p-orbital electrons to the anti-bonding phosphorus-oxygen single bonds. The macromolecular form can be formed by heating the chemical for many hours in a sealed tube and holding the melt at a high temperature before cooling it to solid form. The orthorhombic "O"-metastable form (density 2.72g/cm3
) has a multilayer structure made up of interconnecting P6O6 rings, similar to some polysilicates. The stable form is a higher-density orthorhombic phase known as the O form. It is made up of a three-dimensional structure with a density of 3.5 g/cm3
. The last polymorph is a glass or amorphous form that may be created by fusing any of the others.
Phosphorus pentoxide may be synthesised by burning elemental tetra-phosphorus in an oxygen-rich atmosphere. This chemical is a pure phosphoric acid source. The chemical reaction is given below:
P4 + 5O2 → P4O10
It is employed as a desiccant. It is a good moisture absorbent. It is used in desiccators in granular form.
It is a powerful dehydrating agent. However, its application is limited due to its tendency to develop a viscous coating throughout the reaction.
It is utilised in organic chemical synthesis.
Its dimethyl sulfoxide solution is used to oxidise alcohols.
Many mineral acids can be converted into anhydrides by their desiccating powder.
It is employed in the synthesis of phosphorus compounds.
It is utilised in the production of optical and heat-insulating glass.
It functions as a drying agent for various compounds, particularly those with which it does not react.
It is used in pharmaceuticals.
It is also used in insecticides.
For a reason, P4O10 is also known as phosphorus pentoxide. Phosphorus pentoxide molecules with the formula P2O5 will link together to produce bigger molecules of P4O10.
The IUPAC name of Phosphorus pentoxide is Tetraphosphorus decaoxide.
Phosphorus pentoxide is soluble in water and undergoes exothermic hydrolysis in water.
When it comes into contact with the eyes or skin, it can cause irritation and burning. Even at extremely low concentrations, it can affect mucosal membranes and the respiratory tract.
Phosphorus pentoxide is insoluble in organic solvents like acetone, acetic acid, chloroform and benzene.
Phosphorus pentoxide is an acidic oxide or a phosphoric acid anhydride.