Capillary Action

Capillary Action

Edited By Vishal kumar | Updated on Jul 02, 2025 06:36 PM IST

Capillary action is a fascinating phenomenon where liquid rises in narrow tubes or porous materials against the force of gravity. This process occurs due to the cohesive forces within the liquid and the adhesive forces between the liquid and the surface of the material. For instance, capillary action is crucial in plants, where water is transported from roots to leaves through tiny vessels. In everyday life, this principle is observed in action when a paper towel absorbs spilt liquid or when ink climbs up a fountain pen nib. Understanding capillary action not only unveils the intricate workings of natural systems but also highlights the role of fundamental physics in daily life, from the way our morning coffee percolates to the efficiency of various absorbent materials.

This Story also Contains
  1. Capillary Action
  2. Solved Examples Based on Capillary Action
  3. Summary
Capillary Action
Capillary Action

Capillary Action

Capillary action is a unique physical phenomenon where liquid rises or moves through narrow spaces or porous materials against the force of gravity. This occurs due to the interplay of cohesive forces within the liquid and adhesive forces between the liquid and the walls of the material. In nature, this action is vital for the movement of water and nutrients in plants, allowing them to thrive even in a challenging environment.

Capillarity

Capillarity, or capillary action, refers to the ability of a liquid to flow in narrow spaces without the assistance of external forces, such as gravity. This phenomenon arises from the interplay between cohesive forces within the liquid and adhesive forces between the liquid and the walls of the container or material. A common example is how water rises in the thin tubes of plants, facilitating the transport of essential nutrients from the roots to the leaves. If a capillary tube is dipped in a liquid, it is found that the liquid in the capillary either ascends or descends relative to the surrounding liquid. This phenomenon is called capillarity.

Examples of capillarity

A towel soaks water.

Ascent Formula

When one end of the capillary tube of radius r is immersed into a liquid of density $\rho$ (For example- water and a capillary tube of glass), the shape of the liquid meniscus in the tube becomes concave upwards as shown in the figure.

Then the height h up to which the liquid level rises in the capillary tube is given by Ascent Formula

which says $h=\frac{2 T \cos \theta}{\rho g r}$

where

$T$ - sur face Tension
$r$ - radius of capillary tube
$\rho$ - liquid density
$\theta$ - Angle of contact

The capillary rise depends on the nature of liquid and solid both. I.e on $T, \rho, \theta, r$

For a given liquid and solid pair as $T, \rho, \theta, r$ is constant then. i.e., the greater the radius of capillary greater the rise and vice-versa.

Capillary action for various liquid-solid pair

For $\theta<90^{\circ}$ (1.e for water and capillary tube of glass)
So Meniscus will take Concave shape and liquid in the capillary will rise/ascend.
For $\theta>90^{\circ}$ (l.e for Mercury and glass capillary tube)
So Meniscus will take Convex shape and liquid in the capillary will fall/descend.
For $\theta=90^{\circ}$ (i.e. for Pure water and silver-coated capillary tube.)

So Meniscus will take a Plane shape and the liquid in the capillary will show No rise and no fall.

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Solved Examples Based on Capillary Action

Example 1: A capillary tube made of glass of radius 0.15 mm is dipped vertically in a beaker filled with methylene iodide (surface tension = 0.05 Nm-1, density = 667 kg m-3 ) Which rises to height h in the tube. It is observed that the two tangents drawn from liquid-glass interfaces (from opp. sides of the capillary ) make an angle of 60o with one another. Then h is close to (g=10 ms-2).

1)0.172 m

2)0.049 m

3)0.087 m

4)0.137 m

Solution:

So Angle of contact=30
So using

$
h=\frac{2 T \cos \theta}{r \rho g}=\frac{2 \times 0.05 \times\left(\frac{\sqrt{3}}{2}\right)}{0.15 \times 10^{-3} \times 667 \times 10}=0.087 \mathrm{~m}
$
Hence, the answer is the option (3).

Example 2: Two narrow bores of diameter 5.0 mm and 8.0 mm are joined together to form a U-shaped tube open at both ends. If this U-tube contains water, what is the difference in the level of the two limbs of the tube?
[ Take surface tension of water $T=7 \cdot 3 \times 10^{-2} \mathrm{Nm}^{-1}$, angel of contact $=0, g=10 \mathrm{~ms}^{-2}$ and density of water $=1 \cdot 0 \times 10^3 \mathrm{~kg} \mathrm{~m}^{-3}$ ]

1) $5 \cdot 34 \mathrm{~mm}$
2) $3 \cdot 62 \mathrm{~mm}$
3) $2 \cdot 19 \mathrm{~mm}$
4) 4.97 mm

Solution:

$\begin{aligned} r_1 & =\frac{5}{2} \times 10^{-3} \mathrm{~m} \\ r_2 & =\frac{8}{2} \times 10^{-3} \mathrm{~m} \\ h_1 & =\frac{2 T \cos \theta}{r_1 \rho g} \quad \frac{h_1-h_2}{h_2}=\frac{r_2-r_1}{r_1} \\ h_2 & =\frac{2 T \cos \theta}{r_2 \rho g}=\frac{1 \cdot 5}{\frac{5}{2}} \\ \frac{h_1}{h_2} & =\frac{r_2}{r_1} \frac{\Delta h}{h_2}=\frac{3}{5} \\ h_2 & =\frac{2 \times 7 \cdot 3 \times 10^{-2} \times \cos 0^{\circ}}{4 \times 10^{-3} \times 10^3 \times 10} \\ h_2 & =3 \cdot 65 \mathrm{~mm} \\ \Delta h & =\frac{3}{5} \times 3 \cdot 65 \\ & =\frac{10 \cdot 95}{5} \\ \Delta h & =2 \cdot 19\end{aligned}$

Hence, the answer is the option (3).

Example 3: If M is the mass of water that rises in a capillary tube of radius r, then the mass of water which will rise in a capillary tube of radius 2r will be xM, then find the value of x :

1) 1

2) 0.5

3) 4

4) 2

Solution:

$\begin{aligned} & \frac{2 T \cos \Theta}{\rho g r} \\ & T-\text { wherein face } T \text { tension } \\ & r-\text { radius of capillary tube } \\ & \rho-\text { liquid density } \\ & \theta-\text { Angle of contact }\end{aligned}$

$\begin{aligned} m & =\rho A h \\ m & =(\rho)\left(\pi r^2\right) \frac{(2 T \cos \theta)}{\rho g r} \\ m & \propto r \\ \frac{m_1}{m_2} & =\frac{r_1}{r_2} \\ \frac{M}{m_2} & =\frac{r}{2 r} \\ M_2 & =2 M\end{aligned}$

Hence, the answer is the option (4).

Example 5: Water flows in a streamlined manner through a capillary tube of radius a, the pressure difference being P and the rate of flow Q. If the radius is reduced to a/2 and the pressure increased to 2P, then the rate of flow becomes:

1) $4 Q$
2) $Q$
3) $\frac{Q}{4}$
4) $\frac{Q}{8}$

Solution:


Use, $V=\frac{\pi P r^4}{8 \eta l}$

$
\begin{array}{ll}
\therefore & V \propto P r^4 \\
\therefore & \frac{V_2}{V_1}=\left(\frac{P_2}{P_1}\right)\left(\frac{r_2}{r_1}\right)^4=2 \times\left(\frac{1}{2}\right)^4=\frac{1}{8} \\
\therefore & V_2=\frac{Q}{8}
\end{array}
$
Hence, the answer is the option (4).

Summary

Capillary action, also known as capillarity, is the process where liquids move through narrow spaces or porous materials against gravity due to cohesive and adhesive forces. This principle is crucial in various natural and practical contexts, such as water transport in plants and the absorption of liquids by paper towels. The height to which a liquid rises in a capillary tube is determined by factors like surface tension, liquid density, and the tube's radius, as described by the ascent formula. Practical examples, such as the rise of liquids in capillary tubes or the effect of tube diameter on liquid height, illustrate the diverse applications and significance of capillary action in both scientific and everyday scenarios.


Frequently Asked Questions (FAQs)

1. What is capillary action?
Capillary action is the ability of a liquid to flow upward, against the force of gravity, in narrow spaces without the need for external forces. This phenomenon occurs due to the combination of adhesive forces (between the liquid and the surface) and cohesive forces (within the liquid itself).
2. Why does water rise in a glass capillary tube?
Water rises in a glass capillary tube because of the strong adhesive forces between water molecules and glass. These forces are stronger than the cohesive forces between water molecules, causing the water to climb up the sides of the tube against gravity.
3. How does the diameter of a capillary tube affect the height of liquid rise?
The diameter of a capillary tube is inversely proportional to the height of liquid rise. As the diameter decreases, the height of the liquid column increases. This is because the surface tension effects become more significant in narrower tubes, allowing the liquid to climb higher.
4. Can capillary action make water flow downward?
Yes, capillary action can make water flow downward. While we often associate capillary action with upward movement, it can occur in any direction, including downward or sideways. The direction of flow depends on the balance between adhesive and cohesive forces, as well as the orientation of the capillary surface.
5. Why doesn't mercury exhibit capillary rise in glass tubes?
Mercury doesn't exhibit capillary rise in glass tubes because its cohesive forces (attraction between mercury atoms) are stronger than its adhesive forces with glass. This results in a convex meniscus and a depression of the mercury level in the tube rather than a rise.
6. What is the Jurin's law, and how does it relate to capillary action?
Jurin's law describes the relationship between the height of capillary rise and the radius of the tube. It states that the height of the liquid column is inversely proportional to the radius of the tube. Mathematically, it's expressed as h = (2γ cos θ) / (ρgr), where h is height, γ is surface tension, θ is contact angle, ρ is density, g is gravitational acceleration, and r is tube radius.
7. Can capillary action be used to separate mixtures of liquids?
Yes, capillary action can be used to separate mixtures of liquids, particularly in techniques like paper chromatography or thin-layer chromatography. Different components of the mixture travel at different rates due to variations in their interactions with the stationary phase (e.g., paper fibers), allowing for separation. This principle is also used in more advanced separation techniques in analytical chemistry.
8. What is the difference between capillary rise and capillary depression?
Capillary rise occurs when adhesive forces between the liquid and the surface are stronger than cohesive forces within the liquid, causing the liquid to climb up (e.g., water in glass). Capillary depression happens when cohesive forces dominate, causing the liquid level to be lower in the capillary than outside (e.g., mercury in glass).
9. How does the presence of surfactants affect capillary action?
Surfactants can significantly alter capillary action by changing the surface tension of the liquid. Generally, surfactants reduce surface tension, which can enhance capillary action by allowing the liquid to spread more easily. However, the specific effect depends on the surfactant concentration and its interaction with both the liquid and the surface of the capillary.
10. How does surface tension relate to capillary action?
Surface tension is closely related to capillary action. It is the property that allows the surface of a liquid to resist an external force, caused by the cohesive forces between molecules. In capillary action, surface tension helps create the upward force that pulls the liquid against gravity in narrow spaces.
11. What role does adhesion play in capillary action?
Adhesion plays a crucial role in capillary action. It is the attraction between the liquid molecules and the surface of the capillary tube. Strong adhesive forces cause the liquid to "wet" the surface and climb up the sides of the tube, overcoming gravity.
12. How does capillary action differ in hydrophilic and hydrophobic surfaces?
In hydrophilic surfaces (like glass), water molecules are strongly attracted to the surface, leading to capillary rise. In hydrophobic surfaces (like wax-coated materials), water molecules are repelled, resulting in capillary depression or no capillary action at all.
13. Can capillary action occur in plants that are taller than 10 meters?
While capillary action contributes to water transport in plants, it alone cannot account for water movement in trees taller than about 10 meters. In taller plants, additional mechanisms like root pressure and transpiration pull are necessary to move water to greater heights.
14. How does temperature affect capillary action?
Temperature affects capillary action by changing the liquid's surface tension and viscosity. Generally, as temperature increases, surface tension decreases, which can reduce the height of capillary rise. However, the decreased viscosity at higher temperatures can allow for faster capillary action.
15. What is the meniscus, and how does it relate to capillary action?
The meniscus is the curve formed by a liquid in a container. In capillary action, the shape of the meniscus (concave or convex) indicates whether the liquid will rise or be depressed in the tube. A concave meniscus (like water in glass) leads to capillary rise, while a convex meniscus (like mercury in glass) leads to capillary depression.
16. How does capillary action help in soil water retention?
Capillary action helps in soil water retention by allowing water to move through small pores in the soil against gravity. This process helps distribute water more evenly throughout the soil profile, making it available to plant roots and preventing rapid drainage.
17. Why do paper towels absorb liquids?
Paper towels absorb liquids through capillary action. The small spaces between the paper fibers act as capillary tubes, drawing the liquid upward and outward against gravity. This process continues until the capillary forces are balanced by the weight of the absorbed liquid.
18. How does the roughness of a surface affect capillary action?
Surface roughness can enhance capillary action by increasing the surface area available for adhesion. Rough surfaces provide more contact points and small crevices that can act as capillary channels, potentially leading to greater liquid uptake compared to smooth surfaces.
19. Can capillary action occur in zero gravity?
Yes, capillary action can occur in zero gravity. In fact, it becomes even more prominent in the absence of gravity because there's no opposing gravitational force. In space, capillary forces can cause liquids to behave in unexpected ways, such as climbing container walls or forming spherical droplets.
20. How does capillary action contribute to the movement of groundwater?
Capillary action contributes to groundwater movement by allowing water to rise above the water table into the unsaturated zone of soil. This creates a capillary fringe where water can move horizontally and vertically through small pores, affecting soil moisture distribution and plant water availability.
21. What is the capillary length, and why is it important?
The capillary length is a characteristic length scale that determines the relative importance of gravity and surface tension effects. It's important because it helps predict whether capillary effects will dominate in a given situation. For water at room temperature, the capillary length is about 2.7 mm.
22. How does capillary action affect the boiling point of liquids in narrow tubes?
Capillary action can affect the boiling point of liquids in narrow tubes by increasing the pressure on the liquid. This increased pressure, caused by the curved meniscus, slightly raises the boiling point compared to the same liquid in a wider container.
23. Can capillary action occur between two plates instead of in a tube?
Yes, capillary action can occur between two closely spaced plates, not just in tubes. This is sometimes called capillary rise between plates. The liquid will rise between the plates, forming a curved surface. The height of rise is inversely proportional to the distance between the plates.
24. How does capillary action help in chromatography?
In chromatography, capillary action helps move the mobile phase (often a liquid) through the stationary phase (e.g., paper or a thin layer of adsorbent material). As the liquid moves up by capillary action, it carries dissolved substances with it. Different substances move at different rates, allowing for separation and analysis.
25. How does the shape of a capillary tube affect capillary action?
The shape of a capillary tube can significantly affect capillary action. While circular tubes are most common, non-circular shapes (like square or triangular) can also exhibit capillary action. The corners in non-circular tubes can enhance capillary rise due to increased surface area for adhesion.
26. Can capillary action occur with gases?
While capillary action is typically associated with liquids, a similar phenomenon can occur with gases in extremely narrow spaces (nanoscale). This is sometimes called "capillary condensation" and involves the adsorption and condensation of gas molecules in small pores or cracks.
27. How does capillary action contribute to the formation of stalactites and stalagmites?
Capillary action plays a role in the formation of stalactites and stalagmites by helping water move through tiny pores in limestone. As water seeps through, it carries dissolved minerals. When the water evaporates or loses carbon dioxide, these minerals are deposited, gradually building up these cave formations.
28. How does capillary action affect the preservation of ancient artifacts?
Capillary action can affect the preservation of ancient artifacts by facilitating the movement of water and dissolved salts through porous materials like stone, ceramics, or wood. This can lead to deterioration through processes like salt crystallization or freeze-thaw cycles. Conservators must consider capillary effects when developing preservation strategies.
29. Can capillary action be used to generate electricity?
While capillary action itself doesn't generate electricity, it can be harnessed in certain energy harvesting systems. For example, researchers have developed devices that use capillary action to move water through nanochannels, generating an electric current through interactions with charged surfaces. This concept is still in the research phase but shows potential for small-scale energy generation.
30. How does capillary action influence the design of microfluidic devices?
Capillary action is crucial in the design of microfluidic devices, which manipulate small volumes of fluids. These devices often rely on capillary forces to move liquids through narrow channels without external pumps. Understanding and controlling capillary action is essential for designing efficient lab-on-a-chip devices for medical diagnostics, chemical analysis, and other applications.
31. What is the capillary limit, and why is it important in heat pipe design?
The capillary limit refers to the maximum amount of liquid that can be transported by capillary action in a given system. In heat pipe design, this limit is crucial because it determines the maximum heat transfer capacity of the pipe. If the capillary limit is exceeded, the working fluid cannot return to the evaporator section fast enough, leading to dry-out and reduced efficiency.
32. How does the contact angle affect capillary action?
The contact angle, which is the angle between the liquid surface and the solid surface at the point of contact, significantly affects capillary action. A smaller contact angle (less than 90°) indicates stronger adhesion and leads to capillary rise. A larger contact angle (greater than 90°) indicates weaker adhesion and can lead to capillary depression.
33. Can capillary action occur in non-Newtonian fluids?
Yes, capillary action can occur in non-Newtonian fluids, but its behavior may be more complex than in Newtonian fluids. The variable viscosity of non-Newtonian fluids under different stresses can affect the capillary rise. For example, shear-thinning fluids might show enhanced capillary action under certain conditions due to reduced viscosity in narrow spaces.
34. How does capillary action contribute to the formation of biofilms?
Capillary action contributes to biofilm formation by helping to distribute water and nutrients within the matrix of extracellular polymeric substances (EPS) produced by microorganisms. It allows liquids to move through small spaces between cells and EPS components, facilitating the growth and spread of the biofilm on surfaces.
35. What is electrocapillarity, and how does it relate to regular capillary action?
Electrocapillarity is the change in capillary action due to applied electrical potential. Unlike regular capillary action, which depends solely on surface tension and adhesion, electrocapillarity allows for dynamic control of liquid behavior by altering the surface tension through electrical means. This phenomenon is used in some microfluidic devices and display technologies.
36. How does capillary action affect the drying of materials?
Capillary action plays a significant role in the drying of materials, especially porous substances. As surface moisture evaporates, capillary forces draw water from the interior to the surface. This process continues until the capillary forces are balanced by other forces (like vapor pressure), affecting the drying rate and final moisture distribution in the material.
37. Can capillary action occur in supercritical fluids?
Capillary action as we typically understand it doesn't occur in supercritical fluids because they lack a distinct liquid-gas interface and surface tension. However, supercritical fluids can exhibit enhanced flow through porous media due to their unique properties, which is sometimes compared to capillary-like behavior.
38. How does capillary action influence the design of space suits?
Capillary action is an important consideration in space suit design, particularly in the cooling systems. Liquid cooling garments often use capillary action to distribute cooling fluid evenly through a network of tubes. Additionally, managing sweat and condensation within the suit relies on understanding how these liquids might move via capillary action in microgravity.
39. What is the role of capillary action in 3D printing?
In some 3D printing technologies, especially those using liquid resins, capillary action plays a role in filling small gaps and ensuring smooth layer adhesion. It can help the liquid material to fully wet and spread across the previous layer, improving print quality. However, excessive capillary action can also lead to over-extrusion in some cases, requiring careful control in printer design and settings.
40. How does capillary action affect the behavior of liquids in porous media?
In porous media, capillary action significantly influences liquid behavior by controlling fluid distribution and retention. It causes liquids to spread through interconnected pores, often against gravity. The strength of capillary forces relative to other forces (like gravity or viscous forces) determines fluid saturation patterns, which is crucial in fields like soil science, petroleum engineering, and materials science.
41. What is the Lucas-Washburn equation, and how does it relate to capillary action?
The Lucas-Washburn equation describes the time-dependent penetration of a liquid into a porous medium due to capillary action. It relates the distance traveled by the liquid front to the square root of time, surface tension, viscosity, and pore radius. This equation is crucial in understanding the dynamics of capillary rise in various applications, from oil recovery to ink absorption in paper.
42. How does capillary action contribute to the formation of frost heave in soils?
Capillary action contributes to frost heave by drawing water upward in soil as the freezing front advances downward. As this water freezes, it expands, creating ice lenses that push the soil upward. The continuous supply of water through capillary action allows this process to continue, potentially causing significant ground displacement in freeze-thaw cycles.
43. Can capillary action occur in nanoscale systems?
Yes, capillary action can occur in nanoscale systems, often with enhanced effects due to the extremely small dimensions involved. At the nanoscale, the surface area to volume ratio is very high, making surface forces (including those responsible for capillary action) dominant over bulk forces like gravity. This leads to unique behaviors and applications in nanofluidics and nanotechnology.
44. How does capillary action affect the performance of fuel cells?
In fuel cells, especially proton exchange membrane (PEM) fuel cells, capillary action plays a crucial role in water management. It helps distribute water through the porous gas diffusion layers and catalyst layers, ensuring proper hydration of the membrane. However, excessive water accumulation due to capillary forces can lead to flooding, which impairs gas transport and reduces cell performance.
45. What is capillary condensation, and how does it differ from regular capillary action?
Capillary condensation is the phenomenon where vapor condenses to a liquid in small pores at pressures below the saturated vapor pressure of the bulk liquid. While regular capillary action involves the movement of an
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