The dual nature of matter and radiation is a pivotal concept in physics that defines the relationship between light and matter. It states that both light and matter can exhibit properties of waves as well as particles. This idea emerged from key experiments like the photoelectric effect and the double-slit experiment. In this article, we will explore about dual nature of matter and radiation.
JEE Main 2025: Physics Formula | Study Materials | High Scoring Topics | Preparation Guide
JEE Main 2025: Syllabus | Sample Papers | Mock Tests | PYQs | Study Plan 100 Days
NEET 2025: Syllabus | High Scoring Topics | PYQs
As the name suggests Dual Nature of Matter and Radiation chapter deals with the duality in the nature of matter, namely particle nature and wave nature. Various experiments by various scientists were done to prove it. For example, light behaves both as a wave and as a particle. If you are observing phenomena like interference, diffraction, or reflection, you will find that light behaves as a wave. However, if you are looking at phenomena like the photoelectric effect, you will find that light behaves as a particle.
But light does not only show particle nature it also shows wave nature and you will get to know about it through various experiments.
Dual Nature of Matter and Radiation is one of the most important chapters from modern physics while preparing for all competitive exams because it helps you to understand the dual nature of matter. With the help of either wave nature or particle nature, we can explain the various phenomena that we will study in physics. This is easy to understand and a high-scoring topic. The Concept of the Dual Behaviour of Matter and Radiation and other chapters of physics are mixed in miscellaneous questions that are asked in various competitive exams.
So we will discuss step by step about important topics from this chapter followed by an overview of this chapter. Then we will understand important formulas from this chapter. Remembering these formulas will increase your speed while question-solving.
The dual nature of radiation,
Photoelectric effect,
Hertz and Lenard's observations,
Einstein’s photoelectric equation- the particle nature of light
Experimental study of the photoelectric effect
Matter-wave: the wave nature of particles
De Broglie relation, Davisson and Germer experiment.
Also read,
Free electrons in the metals are responsible for their electrical conductivity. But, the free electrons normally, can not escape from metal. A certain energy is required for the emission of electrons. The minimum energy required to escape an electron from a metal surface is called the work function $\phi_0$ of that metal and is expressed in $eV$ (electron volt).
The minimum energy required for the electron emission can be supplied by one of the following methods:
(i) By heating(thermionic emission)
(ii) By applying a very strong electric field of the order of 108 V m-1 (field emission)
(iii) By irradiating the surface with light rays of suitable frequencies (photoelectric emission)
According to Planck, light consists of tiny packets of energy called quanta or photons of energy value $h \nu$ and momentum $\frac{\mathrm{h}}{\lambda}$.
Momentum of photon $$P=mc$$
$$P=\frac{\mathrm{h}}{\lambda}$$
or $$\lambda=\frac{h}{m c}$$
where,
$\lambda$ is the attribute of a wave
$mc$ is an attribute of the particle
This shows the dual nature of radiation
Discovered by Hertz. The phenomenon of emission of electrons from the surface of the metals when irradiated with $\gamma$ rays, $X$- rays, $U.V$ rays, or visible rays is called the photoelectric effect. Electrons are only emitted if the incident light has a frequency greater than a certain threshold frequency specific to the material. Below this frequency, no electrons are emitted, regardless of the light's intensity.
The phenomenon of photoelectric emission was discovered in 1887 by Heinrich Hertz (1857-1894), during his electromagnetic wave experiments. In his experimental investigation on the production of electromagnetic waves through a spark discharge, Hertz observed that high voltage sparks across the detector loop were enhanced when the emitter plate was illuminated by ultraviolet light from an arc lamp.
Lenard conducted experiments on the photoelectric effect after Hertz, further exploring how light interacts with metals. He observed that when ultraviolet light was shone on a metal surface, it resulted in the emission of electrons, confirming that light could impart energy to electrons. Lenard noted that the emitted electrons were more energetic with higher-frequency light. He also discovered that the number of emitted electrons increased with the intensity of the light, while their maximum kinetic energy remained constant.
Einstein's photoelectric equation describes the relationship between the energy of incident photons and the kinetic energy of emitted electrons. The equation is given by
$$E_k=h f-\phi$$
where,
$E_k$ is the kinetic energy of the emitted electrons
$h f$ is the energy of the incoming photons
$\phi$ is the work function of the material
From the particle nature of radiation, Louis de Broglie argued that what is true for radiation must be true for particles also. ie, for a particle of mass m moving with a velocity $v$, a wave must be associated with it. This wave is called de Broglie wave or matter wave. The wavelength of the de Broglie wave,
$$\lambda=\frac{h}{m v}$$
The velocity of the electron accelerated through a p.d of V volts. $v=\sqrt{\frac{2 e V}{m}}$
De Broglie wavelength of the electrons $\lambda=\frac{h}{m v} = \frac{h}{\sqrt{2 m e V}}=\frac{12.27}{\sqrt{V}}$ Å
For V =100 vlts , $\lambda$ = 1.227Å
This was verified by Davisson and Germer.
Davisson and Germer allowed the electron beam accelerated through 54 volts to fall on a nickel crystal. They measured the maximum intensity of the diffracted electron beam at an angle $\theta$ = $50^{\circ}$. Then the glancing angle $\phi=\frac{180-\theta}{2} = 65^{\circ}$. Using this value in Bragg's equation for x-ray diffraction we get $\lambda$ as 1.65 Å. This is a close agreement with the theoretical value of 1.66 Å.
An evacuated glass or quartz tube contains a photosensitive cathode (C) and a collector plate (A). A battery connects to the cathode to help evacuate photoelectrons. A quartz window allows light to pass through and hit the cathode. A microammeter measures the photocurrent that's produced when the emitted photoelectrons hit the anode.
'
(i) Effect of intensity of light
The photoelectric current emitted is directly proportional to the intensity of light.
(ii) Effect of P.D between A and B
$$E=h \nu=\frac{h c}{\lambda}$$
$$m=\frac{E}{c^2}=\frac{h}{c \lambda}$$
3.The momentum of photon=
$$P=\frac{E}{C}=\frac{h}{\lambda}$$
4. Work function-
$$w=h \nu_0=\frac{h c}{\lambda_0}$$
5. Einstein's Photoelectric Equation=
$$h \nu=w+\frac{1}{2} m v_{\max }^2$$
6. De - Broglie wavelength-
$$\lambda=\frac{h}{p}=\frac{h}{m v}=\frac{h}{\sqrt{2 m E}}$$
NCERT Notes Subject Wise Link:
For Dual Nature of Matter and Radiation, chapter concepts in NCERT are enough but you will have to practice lots of questions including previous year questions and you can follow other standard books available for competitive exam preparation like Concepts of Physics (H. C. Verma) and Understanding Physics by D. C. Pandey (Arihant Publications).
NCERT Solutions Subject-wise link:
The dual behaviour of matter and radiation refers to the concept that both exhibit properties of particles and waves. We have discussed the dual nature of radiation and matter class 12 topics, the photoelectric effect, Einstein’s equation, the Davisson and Germer experiment, Hertz and Lender’s observations, and de Broglie's relation in this article. We have covered almost all the topics included in the syllabus.
NCERT Exemplar Solutions Subject-wise link:
The dual nature of matter and radiation is a pivotal concept in physics that defines the relationship between light and matter. It states that both light and matter can exhibit properties of waves as well as particles.
Ek=hf−ϕ
Dual Nature of Matter and Radiation Class 12 Topics
The dual nature of matter and radiation refers to the concept that both exhibit properties of particles and waves.
The wavelength of the de Broglie wave,
λ=hmv
13 Nov'24 10:25 AM
25 Sep'24 02:47 PM
25 Sep'24 01:00 PM
24 Sep'24 10:51 PM
24 Sep'24 04:14 PM
07 May'22 09:34 AM