Extrinsic Semiconductors - Definition, Types, FAQs

Extrinsic Semiconductors - Definition, Types, FAQs

Edited By Team Careers360(158594)\ | Updated on Nov 20, 2024 02:59 PM IST

A semiconductor is a type of substance having electrical conductivity between conductors and insulators. In semiconductors electrons from the valence band get energy and jump to the conduction band, then the current starts flowing through the semiconductor. Semiconductors generally have 4 valence electrons in their outermost shells. The addition of a trivalent impurity to a semiconductor creates many p-type semiconductors and the addition of a pentavalent impurity to a semiconductor creates many n-type semiconductors. In this article, we will discuss types of semiconductors, what is extrinsic semiconductor, extrinsic semiconductor examples, n-type semiconductor diagrams, p-type semiconductor diagrams, factors affecting extrinsic semiconductors, difference between n-type and p-type semiconductors, and application of extrinsic semiconductor

Types of Semiconductors

  • Intrinsic semiconductor
  • Extrinsic semiconductor

Semiconductors are of two types: intrinsic semiconductors and extrinsic semiconductors.

What do you mean by doping?

Doping is known as the controlled mixing of impurities in semiconductors. The impurities are called dopants.

What is Extrinsic Semiconductor?

Extrinsic semiconductor definition: Extrinsic semiconductor is a special kind of semiconductor that drastically increases the electric conductivity of the semiconductor by mixing impurities in a controlled manner. When the conductivity of a semiconductor gets increased by doping, then the semiconductor is called an extrinsic semiconductor.

If we define impurity, impurities meaning in a semiconductor is not the constituent particle of the semiconductor, it means other substances like arsenic, phosphorus, etc.

Extrinsic semiconductor examples: Germanium (Ge) and silicon (Si) doped with arsenic (As), phosphorus (P), etc.

Types of Extrinsic Semiconductors

Extrinsic semiconductors are classified into two types depending on the doping and the majority charge carriers.

  • n-type semiconductor
  • p-type semiconductor

N-type Semiconductor

If pentavalent impurities or elements are dropped as impurities in the crystal of an intrinsic semiconductor in a controlled manner, the crystal thus formed is called an n-type semiconductor or n-type extrinsic semiconductor.

semiconductor

Pentavalent impurities are called donors as they have five electrons in the outermost shell.

Examples of n-type semiconductors

Arsenic (As), and phosphorus (P) act as an n-type semiconductor in pure silicon (Si) or germanium (Ge).

P-type Semiconductor

If trivalent impurities or elements are doped as impurities in a crystal in an intrinsic semiconductor in a controlled manner, the crystal thus formed is called a p-type semiconductor or p-type extrinsic semiconductor.

P -type semiconductor

Trivalent impurities examples/ Examples of p-type semiconductors

Boron (Br), aluminum (Al) doped in pure silicon (Si), or germanium (Ge) which works as a p-type semiconductor.

Factors Affecting Extrinsic Semiconductors

  1. Doping Element type
  2. Amount of impurities added
  3. Temperature
  4. Energy band gap
  5. Mobility of charge carriers
  6. Type of semiconductor material
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Applications of Extrinsic Semiconductor

  1. Diodes (P-N junction diode, Zener diode, LED)
  2. Transistors
  3. Photodiodes
  4. Solar cells
  5. Lasers
  6. Phototransistors
  7. Rectifiers
  8. Light detectors

Energy Band Diagram For P-type and N-type Semiconductor

P-type Semiconductor Diagram

N-type Semiconductor Diagram

Difference Between P-type and N-type Semiconductors

n-type Semiconductor p-type Semiconductor
Pentavalent impurities Trivalent impurities
Electrons are the majority of charge carriers Holes are the majority of charge carriers
Holes are the minority charge carriers Electrons are the minority charge carriers
Donor impurities that donate free electrons. Acceptor impurities that create holes.
Conductivity is due to the movement of electrons. Conductivity is due to the movement of holes.
Donor energy levels are close to the conduction band. Acceptor energy levels are close to the valence band.
Used in transistors, diodes, and other electronic devices. Used in LEDs, photodiodes, and other electronic devices.
Silicon is doped with phosphorus or arsenic. Silicon doped with boron or gallium.

Also read:

Frequently Asked Questions (FAQs)

1. What is semiconductor?

The substances having electrical conductivity intermediate between conductors and insulators are called semiconductors.  

2. What is hole?

The release of an electron creates a position known as hole , which is opposite in charge of an electron.

3. What is a forbidden band?

The separation between two consecutive energy levels in a solid is known as a forbidden band.

4. What is valence band?

The energy band that is formed by energy levels in which the electrons of a substance can reside, is called valence band.

5. What is a conduction band?

The energy levels possessed by the free electrons or conduction electrons of a substance constitute the band which is known as conduction band.

6. What happens when germanium doped with indium?

When germanium doped with indium, p-type semiconductor is obtained.

7. What is the number of valence electrons in a semiconductor?

A semiconductor has generally valence electrons of 4.

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