Etard Reaction Mechanism - Overview, Application, Limitation, FAQs

Explain Etard Reaction.

Etard reaction in chemistry is the partial oxidation of a methyl group linked to an aromatic ring with C and a non-polar solvent (such as carbon tetrachloride, carbon disulphide , etc.) to yield aldehyde. The following reaction is-

The Etard complex is formed when an alkene – allylic hydrogen reaction occurs with chromyl chloride, resulting in an alkene – allylic hydrogen reaction. To prevent the Etard complex from oxidizing into a carboxylic acid, it is destroyed in a reducing environment. A saturated solution of aqueous sodium sulphite is commonly used to create this reducing environment. The most frequent solvent for this procedure is carbon tetrachloride, however carbon disulfide and chloroform can also be employed. Purifying the Etard complex before breakdown results in a high-purity aldehyde product (so that its reaction with the unreacted reagent is prevented). This equation can take anything from a few days to several weeks to complete, but the yields are relatively high.

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Etard Reaction Mechanism:

In the Etard reaction, chromyl chloride, a mild oxidizing agent, interacts with toluene in the presence of carbon tetrachloride, a non-polar solvent. The - bonds of chromyl chloride are cleaved homolytically during this reaction. Similarly, homolytic breakage of the methyl group's C-H bonds occurs. The Etard complex, also known as the chromyl complex, is formed as a result of this reaction. Now the etard complex is hydrolyzed, resulting in the elimination of two molecules of Cr(OH)₂Cl₂ and the creation of benzaldehyde. Aldehyde is formed by direct partial oxidation of the methyl group linked to the aromatic ring. Etard reaction equation:

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Applications of Etard Reaction

The conversion of toluene to benzaldehyde by oxidation is particularly beneficial in the food business because benzaldehyde has an almond-like flavour. It's used to make colours, fragrances, and a variety of pharmaceutical chemicals. Aldehydes are more reactive and participate in the formation of aldols. Many chemicals, including phentermine, can be made from benzaldehyde.

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Limitations of Etard Reaction

Although the Etard reaction is a quick and easy way to convert toluene to benzaldehyde. It does, however, have some restrictions. It's difficult to get particular aldehyde products using other reagents than toluene in an etard reaction. When powerful oxidizing agents are used in the process, more stable carboxylic acids are produced.

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