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K2Cr2O7 - Meaning, Structure, Effects, Properties & Uses, FAQs

K2Cr2O7 - Meaning, Structure, Effects, Properties & Uses, FAQs

Edited By Team Careers360 | Updated on Jun 29, 2022 04:03 PM IST

K2Cr2O7

It is extremely common to find potassium compounds that are used for a variety of applications. The production of glass has relied for centuries on potash and other potassium compounds. Ninety-five percent of the potassium compounds that are gathered worldwide are used in the manufacture of fertilizers. K2Cr2O7 compound name is potassium dichromate. A compound of inorganic chemistry, potassium dichromate is extremely important for industrial and laboratory applications. The chemical formula for this orange crystalline solid is K2Cr2O7 chemical name. As an oxidizing agent, it is water-soluble. To prepare chrome alum, chrome yellow, and chrome red, it is used to estimate the volume of ferrous salts, iodides, and sulphides.

What is potassium dichromate formula?

A chemical formula of potassium dichromate has the chemical name K2Cr2O7. Potassium bichromate or dipotassium bichromate are other names for this compound. Coloured bright red-orange, it is an ionic crystalline solid. Despite its odour lessness and insoluble properties in alcohol and acetone, it dissolves in water. This chemical is widely used in leather tanning and potassium chrome alum production. Many industries and laboratories use it as an oxidizing agent. The substance is highly corrosive and non-combustible. To prepare sodium dichromate, follow these steps:

  • Potassium chloride is made by reacting sodium dichromate with potassium chloride

  • Result of roasting chrome ore with potassium hydroxide to yield potassium chromate

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K2Cr2O7 structure:

The two potassium cations form an ionic bond with the negatively charged dichromate anion to form potassium dichromate molecules. A dichromate ion is composed of two chromium atoms bound together with four oxygen atoms. The double bonds between chromium and oxygen both consist of one oxygen atom, and the bond between both chromium atoms is one oxygen atom.

What is Potassium Dichromate Uses?

  1. In cement, it slows the setting time as well as improving the density and texture of the mixture.

  2. The photographic screen-printing industry uses it.

  3. This reagent is a common reagent used in traditional "wet tests" in analytical chemistry.

  4. Some types of wood are stained with it for a deep, rich colour.

  5. Glassware and etching material made from it are used to clean them.

  6. Iron and tungsten are used in pyrotechnic displays.

  7. Astringent, antiseptic, and caustic properties make it useful in medicine.

It is known that when dispersed in nitric acid at approximately 35 percent, potassium dichromate forms Schwerte’s solution, an analytical reagent with properties similar to a crystal violet colour. Reagents like this can be used to test for the presence of different metals, especially for silver purity determinations. It is known that pure silver will make the solution bright red, while sterling silver will make the solution dark red.

Moreover, low-quality coin silver causes the solution to turn brown (mainly due to the presence of copper). Moreover, Schwerte’s solution would turn green if 0.500 silver was added to it. This solution does not change colour as it is made with gold and palladium, but brass changes to dark brown colour as it is made with copper. As a result of introducing lead and tin to nitric acid containing potassium dichromate in 35% (approx.) concentration, yellow solutions result.

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The properties of potassium dichromate - K2Cr2O7

K2Cr2O7 name

Potassium dichromate

Molecular Weight of potassium dichromate or K2Cr2O7 molar mass

294.185 g/mol

Density

2.68 g/cm³

Boiling Point

500 °C

Melting Point

398 °C

Potassium dichromate has many other properties that are listed below.

  1. This compound cannot be dissolved by alcohol or acetone.

  2. There are 219 joules of heat per mole in K2Cr2O7.

  3. There are 291.2 joules per kelvin mole in this compound's standard molar entropy.

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Health effects

  • Traditionally, potassium dichromate is mostly harmful to the respiratory tract, causing ulcers. An increased risk of lung cancer is associated with K2Cr2O7, a known human carcinogen.

  • An individual's health can be seriously harmed or even killed by accidentally eating the substance; animal experiments show that even ingesting fewer than 40 grams of the substance can have toxic effects.

  • A chemical burn can occur in the mouth and gastrointestinal tract following ingestion.

  • It is rare to become acutely poisoned by potassium after swallowing because vomiting usually occurs and renal excretion is rapid.

  • In the long run, potassium causes irregular heartbeats, heart block, and blood pressure drop.

  • It may be harmful to touch the material; after absorption, systemic effects might occur.

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NCERT Chemistry Notes:

Frequently Asked Questions (FAQs)

1. Q1. When potassium dichromate is heated, what happens?

On heating potassium dichromate decomposes to form potassium chromate, chromic oxide and oxygen. Also when  heated strongly it gets decomposed into a yellow coloured compound, an oxide of chromium which is green in colour as well as oxygen gas.

2. Q2. Is K2Cr2O7 a reducing agent?

Potassium dichromate is a potassium salt that is dipotassium salt of dichromic acid. It has the  role as an oxidising agent.

3. Q3. In what applications does potassium dichromate find use?

Among the various applications for potassium dichromate, K2Cr2O7, as an oxidizing agent, is used most widely as a chemical reagent. As with all hexavalent chromium compounds, it is acutely and chronically toxic to fitness.

4. Q4. What is the purity of potassium dichromate?

The two chemicals, potassium dichromate, and water are combined. All portions of the sample are equivalent because potassium dichromate is uniformly dissolved in the bath. There's no doubt that it's homogenous. Pure substance consists of just one chemical compound.

5. Q5. What is the reason for the colour of potassium dichromate?

This red-orange crystal is made of potassium dichromate. Oxygen is transferred by electrons into the vacant d- orbital of the Cr6+ complex, which gives it the colour we see. Charge transfer from ligand to metal is known as a ligand to metal charge transfer (LMCT). Consequently, light and complementary colours are absorbed by electronic transfers.

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