Sodium phosphate is a salt formed when sodium (Na+) and phosphate (PO43−) ions combine. Sodium phosphate formula is Na3PO4. Sodium phosphate and its salt may exist in hydrated or anhydrous form. Commonly known as phospho soda, is saline purgative (purgative is a medicine for better digestion). Sodium phosphate or its other forms are produced when hydrogen atom(s) in phosphoric acid (H3PO4) are replaced by sodium atoms. Removal of one hydrogen atom forms monobasic form of sodium phosphate, removal of two hydrogen atoms forms dibasic form of sodium phosphate and removal of all hydrogen atoms forms tribasic form of sodium phosphate. Being a salt, sodium phosphate and its other forms are crystalline solids or white powders. They are colorless to white in appearance.
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Figure 1 Na3PO4 structure.
Sodium phosphate is also known as sodium orthophosphate, tribasic sodium phosphate, trisodium phosphate. Density of trisodium phosphate is 1.62 g/cm3. Sodium phosphate molecular weight (or molar mass of sodium phosphate) is 163.94 g/mol.
Boiling point of sodium phosphate is 100 °C and the melting point of sodium phosphate is 1,583 °C. The value of trisodium phosphate solubility is ‘soluble in water’.
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Sodium monophosphate salts are mostly derived from orthophosphate (PO43−), dihydrogen phosphate (H2PO4−) and hydrogen phosphate (HPO42−).
Some name and the formula of different sodium phosphate is given below.
monosodium phosphate (anhydrous) NaH2PO4 ,disodium phosphate (anhydrous)Na2HPO4, disodium phosphate (dihydrate) HNa2PO4(H2O)2, disodium phosphate (heptahydrate)HNa2PO4(H2O)7, monosodium phosphate (monohydrate) NaH2PO4(H2O), monosodium phosphate (dihydrate) NaH2PO4(H2O)2, disodium phosphate (octahydrate) HNa2PO4(H2O)8, disodium phosphate (dodecahydrate) HNa2PO4(H2O)12,
A number of important salts are produced when sodium reacts with pyrophosphates; also known as Diphosphates, triphosphates and high polymers.
Some name and formula are given below.
monosodium diphosphate (anhydrous) NaH3P2O7, disodium diphosphate (hexahydrate) Na2H2P2O7(H2O)6, trisodium diphosphate (anhydrous) Na3HP2O7, trisodium diphosphate (monohydrate) Na3HP2O7(H2O), disodium diphosphate (anhydrous) Na2H2P2O7, trisodium diphosphate (nonahydrate) Na3HP2O7(H2O)9, tetrasodium diphosphate (decahydrate) Na4P2O7(H2O)10
Triphosphate salts of sodium like tetraphosphates and sodium triphosphate are also known. Metaphosphates, a name given to cyclic phosphates such as Na3P3O9 trimer sodium trimetaphosphate and tetramer Na4P4O12 also exist.
When NaH2PO4 and Na2HPO4 are heated, polymeric sodium phosphates are formed. To form a specific polyphosphate annealing and heating process is altered. Some of such specific polyphosphate is Graham’s salt, Kurrol’s salt and Maddrell’s salt. Graham salt has a formula NaO(NaPO3)Na2. Kurrol’s salt and Maddrell’s salt has a general formula [NaPO3]n[NaPO3(OH)]2 where n can have a value upto 2000. . Kurrol’s salt and Maddrell’s salt are crystalline polyphosphates with a high molecular weight.
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Sodium phosphate and its other forms are very commonly used in a lot of everyday products. This is because sodium phosphate is inexpensive and is nontoxic when taken in adequate amounts. Some sodium phosphate uses includes:
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As discussed, sodium phosphate is used in bowel preparation for medical procedures like colonoscopy. High levels of sodium phosphate intake carries a hazardous risk of kidney failure. Sodium phosphates also play a major role in eutrophication of water. Eutrophication involves increased algal growth known as algal bloom due to presence of excess phosphate which in turn causes decreased oxygen levels in water. Sodium phosphates generally reach water bodies like ponds, rivers or lakes by washing off detergents, soaps, factories or fertilizers.
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NCERT Chemistry Notes:
Sodium phosphate is a salt formed when sodium (Na+) and phosphate (PO43−) ions combine. Sodium phosphate and its salt may exist in hydrated or anhydrous form. Commonly known as phospho soda, is saline purgative (purgative is a medicine for better digestion). Sodium phosphate or its other forms are produced when hydrogen atom(s) in phosphoric acid (H3PO4) are replaced by sodium atoms. Removal of one hydrogen atom forms monobasic form of sodium phosphate, removal of two hydrogen atoms forms dibasic form of sodium phosphate and removal of all hydrogen atoms forms tribasic form of sodium phosphate. Being a salt, sodium phosphate and its other forms are crystalline solids or white powders. They are colorless to white in appearance. Sodium phosphate chemical formula is Na3PO4.
Na2HPO4 name is Disodium phosphate and Na3PO4 compound name is trisodium phosphate.
Na2PO4, trisodium phosphate is slightly acidic in nature based on its pKa value.
Sodium phosphate molecular weight (or molar mass of sodium phosphate) is 163.94 g/mol.
Na3PO4 is phosphate salt of sodium.
Na2HPO4, monosodium phosphate is neutral that is neither acid nor base.
Sodium phosphide formula is Na3P.
Molecular weight of phosphate is 94.971361 g/mol. It can be calculated by adding molecular weight of phosphorus (molecular weight of one P atom is 30.973761 g/mol) and molecular weight of four oxygen atoms (molar mass of one oxygen is 15.9994 g/mol).
Sodium phosphate enema bp uses are:
Sodium phosphate enema is used to treat constipation.
Sodium phosphate enema is used to clean the gastrointestinal tract usually before colonoscopy.
sodium phosphate monobasic molecular weight is 119.98 g/mol.
As discussed, sodium phosphate is used in bowel preparation for medical procedures like colonoscopy. High levels of sodium phosphate intake carries a hazardous risk of kidney failure. Sodium phosphates also play a major role in eutrophication of water. Eutrophication involves increased algal growth known as algal bloom due to presence of excess phosphate which in turn causes decreased oxygen levels in water. Sodium phosphates generally reach water bodies like ponds, rivers or lakes by washing off detergents, soaps, factories or fertilizers.
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