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Hi !
If you don't like the college alloted to you during the ALL INDIA Counselling process , just don't go the college for document verification and further counselling process. Your name will be discarded automatically by the official authorities , there is no need to go the college and ask for a exit. Just don't go the college at first place, that's all.
All the best !
Check out the following link for more information regarding counselling process:
https://medicine.careers360.com/articles/neet-counselling
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