13656 Views

Balance the given reaction by oxidation number method a.Cl2O7 + H2O2 ClO2- + O2 + H+ (basic medium) b.MnO4- + SO2 Mn2+ + HSO4- (acidic medium)


arnavsingh2100 1st Oct, 2020
Answer (1)
G.Roshini 1st Oct, 2020

The oxidation number of chlorine decreases from +7 to +3 and the oxidation number of O  increases from -1 to 0.SO  CI2O7 is oxidizing agent and H2O2 is reducing agent .

ion electron method

the oxidation half reaction is H2O2--->O2

To balance oxidation number 2 electrons are added

H2O2--->O2+2e-

2 hydroxide ions are added to balance the charge

H2O2+2OH---->O2+2e-

2 water molecules are added to balance the O atoms

H2O2+2OH- --->O2+2H2O+2e-

the reduction half reaction is CI2O7-->CIO2-

THE CI atoms are balanced Cl2O7--->CIO2-

8 electrons are added to balance the oxidation number CI2O7+8e- -->CIO2-

6 hydroxide ions are added to balance the charge CI2O7+8e- --->CIO2-+6OH-

The oxidation half equation is multiplied with 4 and added to the reduction half equation.

oxidation number method

total decrease in oxidation number of CI2O7 is 8

total increase in oxidation number of H2O2 IS 2

H202 AND O2 are multiplied with 4

CI2O7+4H2O2--->CIO2-+4O2

Chlorine atoms are balanced CI2O7+4H2O2--->2CIO2-+4O2

O atoms are balamced by adding 3 water molecules CI2O7+4H2O2--->2CIO2- +4O2+3H2O

H atoms are balanced by adding 2 hydroxide ions and 2 water molecules.CI2O7+4H2O2+2OH- --->CIO2- +4O2+5H2O

Related Questions

UPES Integrated LLB Admission...
Apply
Ranked #28 amongst Institutions in India by NIRF | Ranked #1 in India for Academic Reputation by QS University Rankings | 16.6 LPA Highest CTC
Jindal Global Law School Admi...
Apply
Ranked #1 Law School in India & South Asia by QS- World University Rankings | Merit cum means scholarships | Application Deadline: 30th Nov'24
Chandigarh University Admissi...
Apply
Ranked #1 Among all Private Indian Universities In QS Asia Rankings 2025 | Scholarships worth 210 CR
Great Lakes PGPM & PGDM 2025
Apply
Admissions Open | Globally Recognized by AACSB (US) & AMBA (UK) | 17.3 LPA Avg. CTC for PGPM 2024 | Application Deadline: 1st Dec 2024
ICFAI Business School-IBSAT 2024
Apply
9 IBS Campuses | Scholarships Worth Rs 10 CR
Nirma University Law Admissio...
Apply
Grade 'A+' accredited by NAAC
View All Application Forms

Download the Careers360 App on your Android phone

Regular exam updates, QnA, Predictors, College Applications & E-books now on your Mobile

150M+ Students
30,000+ Colleges
500+ Exams
1500+ E-books