It's difficult to say definitively whether a 94.4148 percentile in JEE Main, with home state, OBC, and female quota, will guarantee a BTech Physics seat at NIT Calicut. While a 94 percentile is a good score, it's not a guarantee of admission to a specific program at a specific NIT.

The final cutoff ranks and percentiles for NIT Calicut vary from year to year and are influenced by factors like the overall JEE Main performance, the number of applicants, and the number of seats available.

Your percentile needs to be converted to a rank, which is what is used for seat allotment during the JoSAA counselling process.

Home state quotas can significantly impact your chances, as seats are reserved for students from the state where the NIT is located.

These quotas further influence seat allocation, and the impact on a program like BTech Physics will depend on the specific number of reserved seats and the overall demand for that program.

I suggest you to use JEE predictor tool which will help you to know your chances in nit Calicut .