Each branch is good and has the value in its own field its completly depend on your interest & capability.  Some of the core branches are:

CSE: It is not only development & coding  but also testing and life-time support, which needs CSE engineers in drove. The major chunk of jobs offered in India, every year, are for CS engineers.

ECE: An electronic engineer can find a job in Consumer electronics manufacturing organization , Telecommunication & IT industries, Internet technologies, Power Electronics, and other industries like steel, petroleum and chemical industry.

EEE: Electrical & Electronics engineers can work in wide range of fields such as power generation, electronics, computers & control systems, telecommunication and Bio-Medical.

ME:India always had robust heavy-manufacturing industries like steel, metal, forging, automobile and mining. All these industries require steady inflow of fresh Mechanical engineering graduates.

Civil Engineering: Civil Engineers are usually required in every field some of them:Government Departments, Local Authorities, Civil Engineering Contractor, Civil Engineering Consultants.

Good Luck!