Correct Answer: Sugarcane – Jaggery

Solution : Let's check each option –
First option: Sugarcane – Jaggery; Jaggery is made from sugarcane but sugarcane is not made from jaggery.
Second option: Sack – Jute; Jute is used to make the sack.
Third option: Road – Asphalt; Asphalt is used to construct roads.
Fourth option: Wall – Brick; Brick is used to create a wall.

So, the first option is different from the other options. Hence, the first option is correct.