Question : If the equilibrium constants for the systems H2 + I2 < = > 2HI and 2HI < = > H2 + I2 are K1 and K2 respectively, the relationship between K1 and K2 is :
Option 1: K1 = K2
Option 2: K1 = 2K2
Option 3: K1 = K2 /2
Option 4: K1 = 1/K2
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Correct Answer: K1 = 1/K2
Solution : The correct option is K1 = 1/K2.
For the chemical reactions: H2 + I2 ⇌ 2HI and 2HI ⇌ H2 + I2
The equilibrium constants are given as K1 and K2, respectively. When a reaction is reversed, the equilibrium constant becomes the reciprocal of the original constant. Mathematically, this relationship is expressed as follows: K1 = 1/K2. So, the relationship between K1 and K2 for the given reactions is that K2 is the reciprocal of K1.
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