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Important Naming reaction in alcohol , phenol and ether


N.Sudhansu Achary 19th Oct, 2024
Answers (3)
monag2673 20th Oct, 2024

Important Naming Reactions in Alcohols, Phenols, and Ethers

1. Lucas Test:

  • Purpose: Differentiates primary, secondary, and tertiary alcohols.
  • Reagent: Anhydrous zinc chloride in concentrated hydrochloric acid.
  • Observation: Primary alcohols react slowly, secondary alcohols react moderately, and tertiary alcohols react immediately to form turbid solutions.

2. Oxidation of Alcohols:

  • Primary Alcohols: Oxidized to aldehydes using mild oxidizing agents like PCC (pyridinium chlorochromate) or KMnO4. Further oxidation to carboxylic acids occurs with strong oxidizing agents like KMnO4 or CrO3.
  • Secondary Alcohols: Oxidized to ketones using mild oxidizing agents like PCC or KMnO4.
  • Tertiary Alcohols: Do not undergo oxidation under normal conditions.

3. Dehydration of Alcohols:

  • Purpose: To form alkenes from alcohols.
  • Reagent: Concentrated sulfuric acid or phosphoric acid.
  • Mechanism: Follows an E1 or E2 mechanism, depending on the nature of the alcohol and reaction conditions.

4. Williamson Ether Synthesis:

  • Purpose: To prepare ethers.
  • Reagents: Alkyl halide and an alkoxide ion.
  • Mechanism: SN2 mechanism.

5. Kolbe-Schmitt Reaction:

  • Purpose: To prepare salicylic acid from phenol.
  • Reagents: Carbon dioxide and sodium hydroxide.
  • Mechanism: Nucleophilic addition of phenoxide ion to carbon dioxide followed by hydrolysis.

6. Reimer-Tiemann Reaction:

  • Purpose: To introduce a formyl group (CHO) into the ortho position of a phenol.
  • Reagents: Chloroform and sodium hydroxide.
  • Mechanism: Formation of dichlorocarbene intermediate, which reacts with the phenol to give the ortho-substituted product.

These reactions are crucial for understanding the chemistry of alcohols, phenols, and ethers and their transformations into other functional groups.\

hope this helps you!!

Prachi Kumari 20th Oct, 2024

Hello,

  1. Alcohols:

    • Hydration of Alkenes:

      • Alkenes react with water in the presence of an acid to form alcohols.

      • Example: Ethylene + H2O -> Ethanol.

    • Reduction of Carbonyl Compounds:

      • Aldehydes and ketones can be reduced to form alcohols.

      • Example: Acetaldehyde + H2 (using catalyst) -> Ethanol.

  2. Phenols:

    • Rearrangement of Phenolic Compounds:

      • Phenols can undergo electrophilic aromatic substitution, introducing various substituents.

      • Example: Phenol + Bromine -> Bromophenol.

    • Kolbe Electrolysis:

      • Electrolysis of sodium phenoxide produces phenolic compounds.

      • Example: Sodium phenoxide -> Hydroxybenzoic acid.

  3. Ethers:

    • Williamson Ether Synthesis:

      • Alkyl halides react with sodium alkoxides to produce ethers.

      • Example: Sodium ethoxide + Methyl iodide -> Ethyl methyl ether.

    • Ethanol Dehydration:

      • Two alcohol molecules can react to form an ether through dehydration.

      • Example: 2 Ethanol -> Diethyl ether + H2O (with heat).

These reactions illustrate the versatility of alcohols, phenols, and ethers in organic synthesis, enabling the formation of diverse compounds with varied functionalities.

Hope it helps !

Tanya Gupta 20th Oct, 2024

Hello,

Important naming reactions in alcohol, phenol, and ether include:

  1. Williamson Ether Synthesis : Formation of ethers by reacting alkyl halides with sodium alkoxides.
  2. Lucas Test : Distinguishes between primary, secondary, and tertiary alcohols based on reactivity with Lucas reagent (ZnCl2 + HCl).
  3. Kolbe's Reaction : Converts phenol to salicylic acid using carbon dioxide.
  4. Reimer-Tiemann Reaction : Introduces a -CHO group to phenol, forming ortho-hydroxy benzaldehyde.

These reactions are key in organic synthesis.

Hope this helps you,

Thank you

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