In chemistry, the charge, also known as the oxidation state or valency, varies across a period and down a group in different ways.
Across a Period:
As you move from left to right across a period, the atomic number increases, and the number of valence electrons also increases. This results in:
1. Increase in electronegativity: Atoms become more electronegative, meaning they have a greater tendency to attract electrons.
2. Increase in oxidation state: The oxidation state of elements generally increases across a period, with some exceptions.
3. Change in charge: The charge on ions formed by elements in a period can vary. For example, in Period 3, the charge on ions formed by elements like Na (sodium) and Mg (magnesium) is +1 and +2, respectively.
Down a Group:
As you move down a group, the atomic number increases, and the number of valence electrons remains the same. This results in:
1. Decrease in electronegativity: Atoms become less electronegative, meaning they have a lower tendency to attract electrons.
2. Similar oxidation state: The oxidation state of elements in a group remains relatively constant, with some exceptions.
3. Similar charge: The charge on ions formed by elements in a group is often similar. For example, in Group 1, the charge on ions formed by elements like Li (lithium), Na (sodium), and K (potassium) is +1.
In summary, the charge on ions formed by elements varies across a period due to changes in electronegativity and oxidation state, while down a group, the charge remains relatively constant due to similar electronegativity and oxidation states.
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