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Hi ! It seems that your brother may not get any college on the basis of JEE main marks in Maharashtra. His percentile is too low with 41%. Minimum requirement to stand in a chance is 70 percentile. Still you can predict the rank by the link given below.
https://www.google.com/url?sa=t&source=web&rct=j&url=https://engineering.careers360.com/jee-main-rank-predictor&ved=2ahUKEwiYsK6UvNHiAhWc8XMBHeSJBNkQFjAAegQIBBAB&usg=AOvVaw2QNQ0E4U1hgytKWWo9jfZm
So hope you understand and best of luck to you.
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