Dear student,
Yes you can fill the application form for other sessions also. You can fill the form when the application window again opens for sessions of april and may in the months of april and may respectively. The application window gor april session will be opened in the last week of march tentatively and for that of may will be opened in the last week of april. You can apply for both the sessions at a time or separately. And if you just want to apply for may session, you can do that even. For more info you can visit the following link:
https://engineering.careers360.com/articles/nta-jee-main

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