According to Careers360 anlysis,Maharaja Sayajirao University of Baroda, Vadodara has got AAAA which makes it a very good college overall cut-offs of national / state level Entrance exams, Accreditation and Reward status, Publication record from Elsevier’s indexing database - Scopus to pursue B.Tech program whereas LD College of Engineering, Ahmedabad has got AAA+ which says this is a good colleges for the same overall so as per the rating you are advised to put MSU at first and then consider LDC.

Also, it would be good if you consider your interest, eligibilitty & convenience before you make any decision.

For reference, you can go through the below links -

https://engineering.careers360.com/colleges/maharaja-sayajirao-university-of-baroda-vadodara

https://engineering.careers360.com/colleges/ld-college-of-engineering-ahmedabad

Good Luck!!!