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Benzoic Acid - Overview, Structure, Preparation, Properties & Uses, FAQs

Benzoic Acid - Overview, Structure, Preparation, Properties & Uses, FAQs

Edited By Team Careers360 | Updated on Jun 20, 2022 04:17 PM IST

Benzoic acid is an organic compound that is available in the daily life of our food and cosmetic products. It is used in many products such as pickles, jams, lipsticks, wash creams, etc. This preservative. In addition, for many organic combination syntheses, it is an essential precursor.

What is Benzoic acid?

The organic compound is benzoic acid with C6H5COOH chemical benzoic acid formula. It consists of a benzene ring carboxylic group. Thus the aromatic carboxylic acid of benzoic acid is seen. The compound exists in normal conditions as a colorless crystalline solid. This term refers to C6H5COOH esters and salts.

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Benzoic acid structure :

The C7H6O2 benzoic acid empirical formula has a C6H5COOH molecular formula. Benzene carboxylic acid is otherwise known. There are 7 carbon atoms, 2 oxygen atoms and 6 hydrogen atoms. It consists of a six-carbon ring with alternate single and double bands, as well as the group of –COOH attached to the ring that makes it benzoic acid.

Benzoic acid formual: C6H5COOH

The benzoic acid structure is given below:

Benzoic acid IUPACBenzoic acid 3D

Preparation of benzoic acid

Here we convert Phenol to benzoic acid.

First we convert phenol to benzene using zinc dust and then we convert benzene to Tolune using the CH3Cl+AlCl3, here aluminum trichloride acts as lewis acid catalyst.

NCERT Chemistry Notes :

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Then Toluene is converted into benzoic acid by oxidation.

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Resonating structure of benzoic acid or Resonance structure of benzoic acid(Resonating structure of benzaldehyde)

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Physical properties of benzoic acid

  1. In its solid state of crystalline nature, benzoic acid reaction has an uncolored appearance.
    It is nonclinical in its crystal structure.
  2. This compound is slightly pleasant because of the aromatic ring.
  3. This compound's density decreases to 1,075 grammes per cubic centimeter at a temperature of 130oC.
  4. Benzoic acid melting point of benzoic acid is 122.30C.
  5. Benzoic acid molar mass - 122.12 g/mol.

Chemical properties of benzoic acid

  1. The solubility is 3.44 g/L and 56.31 g/l, respectively, at a temperature range of 25oC and 100oC.
  2. Benzene, carbon tetrachloride, acetone and alcohol are soluble.

  3. The benzoic acid pka dissociation constant is 4.2.

  4. The carboxyl group or even the Aromatic Ring may experience its reactions.

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Uses of benzoic acid

It is used in an acidic medium, but it has lost preservation activity in an alkaline medium because it divides into ions in an alkaline medium.

  • The use of benzoic acid as a preservative does not affect the odor or taste of food products.

  • It delays the reproduction of microorganisms by preserving the quality.

  • The benzoic acid sodium salt sodium benzoate reduces the blood level of glycine because it is an amide bond between the benzoate and glycine that is excreted by the urinary tract.

  • Some benzoic acid esters act as plasticizers

  • For many foodstuffs such as soda, barbecue sauces, pickle, and dressings which prevent the growth of bacteria and fungi, benzoic acid and its sodium salt are used as food preservatives.

  • Benzoic acid is used to treat skin irritation, sunburns, insect bites, fungal infections, etc.. This is used specifically in cosmetics.

  • It is used as a pH adjuster in the preparation of fragrances.

  • It is mostly used in acidic foods because even at very low pH it has more anti-food and antibacterial properties.

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Frequently Asked Questions (FAQs)

1. 1. Give structure of sodium benzaote?

Sodium benzaote structure is given below:

(self- made using chemdraw)

2. 2. Is benzic acid soluble in water ?

A monobase aromatic acid, moderately strong white crystalline powder, highly soluble in alcohol, ether, and benzene, but poorly soluble in water.

3. 3. How benzoyl chloride is prepared from benzoic acid?

Benzoyl Chloried is prepared from benzoic acid by treating benzoic acid with SOCl2, that is with thyonial chloride.

(selfmade using ChemDraw)

4. 4. How to convert benzoic acid to benzamide?

First we convert benzoic acid to benzoyl chloride using SOCl2 . Then we convert the obtained Benzoyal chloride to benzamide by treating it with NH3

5. 5.Why benzoic acid is insoluble in water?

The main reason for the dissolution of benzoic acid in cold water is because the bulk of the benzoic acid molecule is nonpolar because of the polar carboxylic group. The only group polar is the carboxylic one. Moreover - COO (-), over carboxylic acid, -COOH group, there are no internal stabilisation structures favouring carboxylate groups.

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