The parallel combination of electrochemical cells is battery or cell. For explaining the difference between a primary and secondary cell, first focus on the fact that secondary cells are the one that is rechargeable while the primary cells can be not rechargeable. Secondary cells can be recharged after the charges are over while the primary cells are discarded after the expiration of the lifetime.
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The lifetime of the primary cells is low since The design of the primary cells is smaller and lighter while the design of a secondary cell is more complicated and heavier. In this article, the difference between primary cell and secondary cell and also their characteristics properties are explained in detail. Due to the high waste produced by the primary cell as they have to be disposable immediately after use, the use of primary cells is declining and the use of secondary batteries is increasing nowadays. Before going to explain them in detail first we need to know about what a cell and battery are.
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Some of the difference between primary cell and secondary cell are shown in the following table.
Primary cell | Secondary cell |
Cannot be recharged after getting discharged. | It can be recharged. |
They are cheap. | They are expensive. |
Easy to handle. | It is complicated. |
It has a small lifetime. And are discarded immediately after its use. | It has a high lifetime. And are reusable. |
Self recharge rate is low. And are found in the torch and other portable electronic devices that need electric current immediately. | It possesses a high self-recharge rate. And these are found in inverters and automobiles. |
The working of both the battery and cell is the same and these two terms are often mispronounced sometimes. Both cell and battery are a part of electrochemistry. Cells are a smaller one while the battery is a larger one. The energy conversion of both of them is similar in that they convert chemical energy into electrical energy. The main difference between battery and cell is that a battery is a combination of a group of cells while the cell is a single unit and both convert chemical energy into electrical energy.
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As already mentioned the one that cannot be charged is called a primary cell and is discarded immediately after the expiration lifetime. This type of cell has a high density and it gets discharged slowly also. Primary cells are called dry cells because there is no fluid present inside the primary cell. The chemical reactions performing on this cell are usually irreversible and the internal resistance of the primary cell is high.
The cost of primary cells is cheap and it is very easy to handle. For the primary cell, the irreversible chemical reactions happening on the cells are used for generating electrical energy. One of the very common examples of the primary cells is dry cells once the charge of them was over we might discard them. And compared to secondary cells, primary cells are discarded immediately after the use they create hazardous waste on the surface of Earth. They possess high pollutants and also the energy content of the primary cell is smaller so they are not environmentally friendly and wasteful batteries.
Another important factor that reduces the lifetime of a primary cell is polarization. That is the hydrogen gets accumulated on the cardboard of the cell and thereby reduces exam effectiveness. New methods are put forward in order to reduce the effect of polarization by the use of an oxidizing agent and by depolarizing the cell and also the byproduct produced after this is water. Some of the oxidizing agents used for these purposes are nitric acid and manganese dioxide.
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As already mentioned they are not rechargeable cells and they cause low energy density. These cells are made up of molten salt and cells so they are not dry cells as well. The chemical reactions performing on secondary cells are reversible and the internal resistance of the secondary cell is low. It is a little bit complicated to use and the initial cost of the secondary cell is high in comparison to the primary cell.
For the secondary cell, the reversible reaction happening inside the cell is used for the conversion of chemical energy to electrical energy. One of the very common examples of the secondary cell is the battery used in the inverters and is a secondary cell so it is recharged by the application of electricity when the charge is over. The use of secondary cells is going on the increase due to the low pollutant rate and are environmentally benign.
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NCERT Chemistry Notes:
A type battery or type of galvanic cell that is designed for the purpose of use and discards which means it cannot be reused is a primary cell. The chemical reactions of the electrochemical reactions occurring in a primary cell are generally not reversible which is the reason why it does not recharge after the power is over. It mainly uses chemicals for the generation of electricity and the power of those chemicals is over its production of electricity is also over. They are produced in a small size mainly for the applications like portable radios, flashlights, for kids' toys, etc. Primary cells contain toxic heavy metals and strong acids and strong alkalis so these are not environmentally friendly and only creative hazardous waste on the environment is compared to the secondary cell. Now the market share of primary cells is declining. It is due to the coming of secondary cells and their efficient performance but also due to the production rate of primary cells being 50 times greater than the energy it contains.
A rechargeable battery for storage in which it can be charged after the charge on them is gone is a secondary cell. It is also given the name accumulator since it accumulates and stores energy through a reversible electrochemical reaction. It has the ability to be recharged many times. Secondary cells consist of one or more electrochemical cells and several combinations of electrode materials and electrolytes can be used. The rechargeable lithium battery used in mobile phones is a very common one. However, the cost of rechargeable batteries is higher than the primary cell but it is very environmentally friendly. To explain the working of a secondary cell the positive active materials are first oxidized and thereby produce electrons and the negative materials are produced by accepting electrons. And it will then constitute the current flow on it. The charging of them is performed by applying electric current and proper charging is a necessity if it is not managed properly leads to damage to the battery or catch fire. The energy obtained after recharge is stored as chemical energy and it will convert to electrical energy when it is needed. Due to the high-performance large energy production and also environmental friendly the use of secondary cells is now increasing.
Lead storage batteries and nickel-cadmium storage cells are secondary cell examples.
The cells that cannot be recharged after the charge goes on are primary cells. Daniel cell, dry cell, etc.
It is a primary cell.
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