Hello Jennifer,
Absolutely Yes!
NCERT is the best book for AIIMS exam. Mostly questions in biology especially those related to diagrams come from NCERT. Also, most A and R questions of PCB come from NCERT. For physics and chemistry, you have to consider reference books.
I advise that after studying NCERT, try solving previous questions or NCERT based questions to see your level of understanding of the book.
Wishing you the very best of luck!
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