Remember that the first law of thermodynamics states (Q+W+u^1)=(u^2)(Q+W+u^1)=(u^2)
Where u^u^ is internal energy.
By definition of an adiabatic process, the only way that internal energy can change is via work, which is defined as the integral of P dV
Before we can solve this integral, we need to formulate a relationship between pressure and volume under the condition of an adiabatic process. Consider then, the differential form of the first law of thermodynamics (done by considering the limit as the increment of heat and work added to the gas goes to zero, and allowable under the assumption of reversibility), namely
dQ=dW+dU=0=PdV+dUdQ=dW+dU=0=PdV+dU
For an ideal gas, another equation of note is
dU=nCvdTdU=nCvdT
from the definition of Cv=dUdTCv=dUdT
Utilizing the ideal gas equation, we see that
nCvdT=nCvnR(PdV+VdP)nCvdT=nCvnR(PdV+VdP)
Once again substituting into the differential form, we see that
Cv+RRPdV+CvRVdP=0Cv+RRPdV+CvRVdP=0
Which, upon relatively simple integration, results in the equation
PVγ=P0Vγ0PVγ=P0V0γ
and allows integration to find that
P0Vγ0γ−1(V1−γ0−V1−γ1)P0V0γγ−1(V01−γ−V11−γ)
Question : The first law of thermodynamics is simply the case of:
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