Both the colleges are good. You can choose any college according to your branch preference.
If we compare the branches then CSE has more scope in future in terms of placements.
According, to Careers 360 bith the colleges have AAAA ratings which means very good. Both colleges provides good placements.
You can also compare both the colleges from the given below link
HBTU Kanpur, Ratings and Reviews
NIT Raipur, Ratings and Reviews
Good luck!!
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