Hi,

First of all you should decide your preference among EE and ECE .

In my opinion you should take ECE in NIT Raipur.
Also you can be placed quite well in ECE.

According to me you should go with that branch in which you find yourself more interested. "DEEP INTEREST " is key to success in any branches. i think it's interest which led to success in any branch, it is better in term of placements. one thing you should always keep in mind that both the institute are premier institute but NIT Raipur is something different from other institutes(IITs/NITs).It has vision of becoming leading institute in the world by upcoming next 6-7 years and for this vision rapid growth of institute is on it's track, within 3 years NIT Raipur is ranked between 6-9 top NITs by different websites(inclusive of 6 and 9).

ECE: Electronics and Communication Engineering
EEE: Electronics and Electrical Engineering

EEE: Electrical and Electronics Engineering branch deals with Electrical technology and machines, circuit analysis, electronics, electromagnetism, electrical engineering materials, instrumentation, control systems, power engineering and transmission and distribution.

ECE: This branch mainly deals with analog transmission, basic electronics, solid state devices, microprocessors, digital and analog communication, analog integrated circuits, satellite communication, microwave engineering, antennae and wave progression. It also deals with the manufacturing of electronic devices, circuits, and communications equipment.

Placements:

EEE: Electrical graduates are employed in Electricity Boards/Utility companies responsible for installation, maintenance, operation of power handling equipment and systems. Industries manufacturing large electrical machines and equipment employ engineers in design, production and testing. For individuals dreaming of JTO(Junior Training Officer), DRDO(Defence Research and Development Organisation), ISRO(Indian Space Research Organisation) and GATE, EEE is not a good choice. This is because they have a separate paper for ECE, while students pursuing EEE have to study a lot of other things. Besides this, EEE students can’t take IES while ECE students can.

ECE: In ECE, the scope to land into government jobs is great. An electronics engineer can find a job in Central Government, State Governments and their sponsored corporations, private industries dealing in manufacture, sales and services of electronics consumer goods and appliances. Additionally, electronics engineers are also absorbed into the broadcast industry, research establishments, and defence.

NIT Durgapur and NIT Raipur are quite the same with no much difference.

Its all upon your interest and your choice of career.

Hope this helps.

Good luck.